Carboxylic Acid and It’s Derivatives
Topics Covered:-
- Aliphatic and aromatic carboxylic acids
- Introduction, nomenclature and isomerism
- Preparation of monocarboxylic acids from: aldehydes, nitriles, dicarboxylic acid, sodium alkoxide and trihaloalkanes
- Preparation of benzoic acid from alkyl benzene
- Physical properties of monocarboxylic acids
- Chemical properties: Action with alkalies, metal oxides, metal carbonates, metal bicarbonates, PCl3, LiAlH4 and dehydration of carboxylic acid
- Hell-Volhard-Zelinsky reaction
- Electrophilic substitution reaction of benzoic acid – bromination, nitration and sulphonation)
- Effect of constituents on the acidic strength of carboxylic acid
- Abnormal behaviour of methanoic acid
- Derivatives of Carboxylic acids (acid halides, amides, esters and anhydrides)
- Preparation of acid derivatives from carboxylic acid
- Comparative physical properties of acid derivatives
- Comparative chemical properties of acid derivatives (hydrolysis, ammonolysis, amines (RNH2), alcoholysis, and reduction only)
- Claisen condensation
- Hofmann bromamide reaction
- Amphoteric nature of amide
- Relative reactivity of acid derivatives
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Notes By: Bikash Pandeya
